Bis(acetato-κ2 O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)copper(II) monohydrate
نویسندگان
چکیده
In the title compound, [Cu(C(2)H(3)O(2))(2)(C(12)H(12)N(2))(2)]·H(2)O, the Cu(II) atom exhibits a distorted octa-hedral coordination geometry, defined by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine ligand and four O atoms from two acetate ligands. In the crystal, O-H⋯O hydrogen bonds are observed between the coordinated carboxyl-ate O atoms and the solvent water mol-ecule.
منابع مشابه
Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)copper(II)]
The mol-ecule of the title binuclear copper(II) complex, [Cu(2)(C(14)H(8)O(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(2)], is bis-ected by a crystallographic twofold axis. Each Cu(II) atom is coordinated in a distorted octa-hedral geometry by three O atoms from two biphen-yl-2,2'-dicarboxyl-ate anions, one aqua O atom and two N atoms of a 4,4'-dimethyl-2,2'-bipyridine ligand. Intramolecular O-H⋯O hydroge...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012